It has two Vccs because of the isolation circuit (opto-coupler). For your application they can be connected together. The Ctrl input would go to the relay wire on the ALP, and Vcc would go to a 5V supply (you may have to use a 7805 or 78L05 regulator or something). If you're using an Arduino it would have a 5V supply on-board.
A circuit with a 12V relay and a transistor would be simpler to implement since you wouldn't have to provide a 5V supply.
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